Mechanism of the reduction of acetatopentaamminecobalt(III) complex by chromium(II) complex ligating N-2-hydroxyethylethylenediamine-N,N′,N′-triacetate or ethylenediamine-N,N,N′,N′-tetraacetate
✍ Scribed by Hiroshi Ogino; Makoto Shimura; Toshiyuki Watanabe; Nobuyuki Tanaka
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 184 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0020-1650
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## Abstract The substitution of __N__‐alkyl substituted ethylenediamines for chloride ions in the rapidly equilibrating system has been investigated in aqueous acid medium. The kinetic data can be accommodated by the general rate law where __n__ = 0, 1, or 2 and __m__ = 0, 1, or 2, depending on w
## Abstract EPR Spectra have been measured for aqueous solutions of a series of Gd^3+^ complexes at variable temperature and a range of magnetic fields; S‐band (0.14 T), X‐band (0.34 T), Q‐band (1.2 T), and 2‐mm‐band (5.0 T). The major contribution to the observed line widths is magnetic‐field‐depe