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Mechanism of the quenching of positronium by diamagnetic organic molecules

โœ Scribed by V. I. Gol'danskii; O. V. Koldaeva; V. N. Chirkov; V. P. Shantarovich


Book ID
112361941
Publisher
Springer
Year
1975
Tongue
English
Weight
271 KB
Volume
9
Category
Article
ISSN
0040-5760

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๐Ÿ“œ SIMILAR VOLUMES


Carbonium ion and positronium quenching
โœ V.P. Shantarovich; K. Petersen; V.I. Goldanskii ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 232 KB

Positranium was found to be highly sensitive to the presence of carbonium ions in the structures of diamagnetic organic molecules. This sensitivity is due to strong positronium quenching by the carbonium ion.

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Rate constants for the quenching of Oz(lAg) by 2,3dimethyl-2-butene and triethylamine have been determined in a discharge-flow system when NO2 is added to eliminate atomic oxygen from the system. The results indicate that in many previous determinations of rate constants for the quenching of 02(lAg)