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Mechanism of the photoisomerization of 1,3-diphenylallyl carbanion

✍ Scribed by Sucha S. Parmar; Brian Brocklehurst; Ronald N. Young

Publisher
Elsevier Science
Year
1987
Weight
258 KB
Volume
40
Category
Article
ISSN
0047-2670

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## Abstract The title compound **1** is shown to give, both upon direct irradiation at 254 nm and upon acetophenone‐sensitized photolysis at 300 nm, the __syn__‐vinyl‐pentamethylhousene **5**, which spontaneously rearranges in a [3,3]0sigmatropic process to give the bicyclo[3.2.0]heptadiene skeleto