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Mechanism of the Photochemical Formation of Phenanthrene from cis -Stilbene in the Vapor Phase

โœ Scribed by Srinivasan, R.; Powers, J. C.

Book ID
126018017
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
274 KB
Volume
85
Category
Article
ISSN
0002-7863

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Coherent low frequency ( 100-125 cm -~ ) nuclear motion was detected in the cis -~ trans condensed phase isomerization of stilbene. A mode, associated with phenyl torsional motion, has a vibrational dephasing time of 100 fs and exhibits solventdependent wavepacket dynamics. Selective probe wavelengt