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Mechanism of the Oxidation of p,p'-Dichlorobenzyl Sulfide by Peroxybenzoic and para Substituted Peroxybenzoic Acids

โœ Scribed by Overberger, C. G.; Cummins, R. W.

Book ID
115544389
Publisher
American Chemical Society
Year
1953
Tongue
English
Weight
628 KB
Volume
75
Category
Article
ISSN
0002-7863

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Mechanism of oxidation of diphenyl sulfi
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โœ C. Srinivasan; P. Kuthalingam; N. Arumugam ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 377 KB

## Abstract Reactions of diphenyl sulfide with the two oxidants peroxydisulfate and peroxydiphosphate are described. With each oxidant, the reaction is first order in the oxidant and zero order in the substrate. The rate of the reaction is also independent of the effect of the substituent. Hydrogen