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Mechanism of the oxidation of NADH by quinones. Energetics of one-electron and hydride routes

โœ Scribed by Carlson, Brian W.; Miller, Larry L.


Book ID
118126287
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
924 KB
Volume
107
Category
Article
ISSN
0002-7863

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The kinetics of NADH oxidation by 3 Dawson-type mixed heteropolyanions were studied in buffered aqueous pH = 7 medium, by the stopped flow technique and UV-visible spectroscopy. The log of k was a linear function of the E ยฐ of the first redox systems of the heteropolyanions with a slope of 16.5 V-1