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Mechanism of the Opening of the closo-NB11 Clusters by Bases

✍ Scribed by Peter Paetzold; Jens Mueller; Franc Meyer; Petra Lomme


Publisher
John Wiley and Sons
Year
2004
Weight
49 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

For Abstract see ChemInform Abstract in Full Text.


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The Haloboration of Tri-tert-butylazadib
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The azadiboriridine [Β±BRΒ±NRΒ±BRΒ±] (1; R = tBu) is bromoborated at the BΒ±B bond by alkyldibromoboranes R'BBr 2 to give the products BrΒ±BRΒ±NR=BRΒ±BR'Β±Br (8 aΒ±g: R' = Me, Bu, iBu, Bzl, CH 2 CHEt 2 , CH 2 Cy, CH 2 (4-C 6 H 4 tBu)). Two isomers of each of the products 8 aΒ±g are formed and attributed to a c