Mechanism of the Low-Temperature Scavenging of Methyl- d 3 Radicals by Nitric Oxide
β Scribed by Maschke, A.; Shapiro, B. S.; Lampe, F. W.
- Book ID
- 126324024
- Publisher
- American Chemical Society
- Year
- 1963
- Tongue
- English
- Weight
- 379 KB
- Volume
- 85
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
## Abstract Combination reactions of the methyl radical have been studied by following the decay of the absorbance of the methyl radical during the course of the reaction by means of kinetic spectroscopy. The limiting values of the secondβorder rate constants at high pressure were determined for tw
During methane oxidation initiated by nitric acid or nitrogen dioxide, it is possible to observe, under certain conditions of temperature, initiator content, and flow rates, the formation of an adiabatic "temperature peak." Because the maximum temperature of the peak does not exceed the initial temp