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Mechanism of the keto-enol tautomerism in radical cations and gas-phase closed-shell systems

✍ Scribed by Splitter, Janet S.; Calvin, Melvin


Book ID
124063991
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
588 KB
Volume
101
Category
Article
ISSN
0002-7863

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Fragmentation of the acetyl-and propionyl-ferrocenes under electron impact together with the rupture of C-CO bonds, characteristic of ketones, also includes elimination of water and migration of the OH group to the central metal atom, which is due to keto-enol tautomerization of the acyl group in mo