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Mechanism of the isomerization of tropine into pseudotropine

✍ Scribed by É. Kovacs; J. Schneider; F. Ures

Book ID
112422061
Publisher
Springer
Year
1964
Tongue
English
Weight
480 KB
Volume
13
Category
Article
ISSN
1573-9171

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The synthesis and separation of [3-2H]tr
The synthesis and separation of [3-2H]tropine and [3-2H]pseudotropine (ψ-tropine)
✍ Barbara A. Bartholomew; Michael J. Smith; Paul J. Darcy; Peter W. Trudgill; Davi 📂 Article 📅 1994 🏛 John Wiley and Sons 🌐 French ⚖ 246 KB

## Abstract Tropinone was reduced using sodium borodeuteride to give a mixture of the epimers [3‐^2^H] tropine and [3‐^2^H]pseudotropine with the latter compound predominating and constituting about 70% of the mixture. Crystallisation of the product from diethyl ether gave crystals of pure [3‐^2^H]