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Mechanism of the intramolecular 1H nuclear Overhauser effect in peptides and depsipeptides

โœ Scribed by T.Phil Pitner; Roderich Walter; Jerry D. Glickson


Book ID
118310752
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
327 KB
Volume
70
Category
Article
ISSN
0006-291X

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Isotope Effects on the17O,1H Coupling Co
โœ Nickolai M. Sergeyev; Natalia D. Sergeyeva; William T. Raynes ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 65 KB

The NMR spectra of solutions of 30% 17 O-enriched H 2 O and D 2 O in nitromethane display the resonances of the three isotopomers H 2 O, HDO, and D 2 O. All 17 O, 1 H and 17 O, 2 H coupling constants and the primary and secondary isotope effects on J( 17 O, 1 H) have been determined. The primary eff