The Influence of the Axial Ligands of a
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Ellis, LT; Er, HM; Hambley, TW
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Article
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1995
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Commonwealth Scientific and Industrial Research Or
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English
⚖ 612 KB
The electrochemical reduction and DNA binding have been studied for a series of platinum(IV) complexes with Cl-, OH-, and carboxylate anions as the axial ligands ; [Pt(en)Cl4], [Pt(en)Cl2(OH)2], and [Pt(en)Cl2(OC(O)R)2], R = CH3, CH2CH3, CH2CH2CH3. Cathodic reduction potentials vary by more than 650