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Mechanism of the cationic addition-.pi..pi.-transannular cyclization of disubstituted methanes with 1,5-cyclooctadiene

โœ Scribed by Tabushi, Iwao.; Fujita, Kahee.; Oda, Ryohei.


Book ID
127002569
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
899 KB
Volume
35
Category
Article
ISSN
0022-3263

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Stereochemistry of cationic addition -ฯ€,
โœ I. Tabushi; K. Fujita; R. Oda ๐Ÿ“‚ Article ๐Ÿ“… 1967 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 244 KB

The chemistry of carbonlum Ion stabilized by means of an acprouriately located'it-bond or, in some cases, of a c-bond has been remarkably advanced(l). The observed strong C+-'ilinteractlon suuaests that If an unconjuqated diene is treated wlth catlonic rea.qent, transannular cyclizatlon should take