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Mechanism of the benzidine rearrangement. Kinetic isotope effects and transition states. Evidence for concerted rearrangement

โœ Scribed by Shine, Henry J.; Zmuda, Henryk; Park, Koon Ha; Kwart, Harold; Horgan, Ann Gaffney; Collins, Clair; Maxwell, Brian E.


Book ID
118005035
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
296 KB
Volume
103
Category
Article
ISSN
0002-7863

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Is the McLafferty rearrangement of keton
โœ Michael B. Stringer; Dennis J. Underwood; John H. Bowie; Colin E. Allison; Kevin ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 767 KB

Intramolecular I3C and 'H isotope effects have been measured for unimolecular losses of ethene (the McLafferty rearrangement) from metastable molecular ions of 2-ethyI-l-phenylbutan-l-one, kthylpentan-Zone and heptan-4one. Primary and secondary deuterium isotope effects are observed at the y-(termin