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Mechanism of the B(C 6 F 5 ) 3 -Catalyzed Reaction of Silyl Hydrides with Alkoxysilanes. Kinetic and Spectroscopic Studies

✍ Scribed by Chojnowski, Julian; Rubinsztajn, Sławomir; Cella, James A.; Fortuniak, Witold; Cypryk, Marek; Kurjata, Jan; Kaźmierski, Krzysztof

Book ID
120395180
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
170 KB
Volume
24
Category
Article
ISSN
0276-7333

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✍ Jean-Marc Denis; Henrietta Forintos; Helga Szelke; György Keglevich 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 83 KB

HSiR 3 /cat-B(C 6 F) 3 induced dealkylation or reduction of esters of phosphorus at 20°C. A specific conversion to P-silylesters occurred by reaction with tertiary silanes. In contrast, free phosphines were observed in the reaction with mono-or disubstituted silanes. A mechanism was proposed to rati