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Mechanism of the Anionic Wittig Rearrangement. An ab Initio Theoretical Study

✍ Scribed by Antoniotti, Paola; Tonachini, Glauco


Book ID
127083902
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
245 KB
Volume
63
Category
Article
ISSN
0022-3263

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Mechanism of the Allylic Rearrangement o
✍ StΓ©phane Bellemin-Laponnaz; Jean Pierre Le Ny; Alain Dedieu πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 315 KB πŸ‘ 2 views

The mechanism of the isomerization of allyl alcohols by the 1,3transposition of a hydroxy group, which is catalyzed by transition metal complexes in a high oxidation state, has been investigated by ab initio quantum chemical calculations for a trioxorhenium catalyst. The calculations point to a cycl