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Mechanism of stereoregularity in the polymerization of dienes in anionic systems

✍ Scribed by A.Kh. Bagdasar'yan; B.A. Dolgoplosk; V.M. Frolov


Book ID
118358683
Publisher
Elsevier Science
Year
1969
Weight
432 KB
Volume
11
Category
Article
ISSN
0032-3950

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## Abstract Polymerization of cyclohexa‐1,3‐diene using __sec__‐BuLi as initiator in cyclohexane produces both soluble (70–90 wt.‐%) and insoluble (10–30 wt.‐%) fractions depending on the temperature. The insoluble poly(cyclohexa‐1,3‐diene) was crystalline as determined by X‐ray diffraction and dif