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Mechanism of Scandium Ion Catalyzed Diels−Alder Reaction of Anthracenes with Methyl Vinyl Ketone

✍ Scribed by Fukuzumi, Shunichi; Yuasa, Junpei; Miyagawa, Toshio; Suenobu, Tomoyoshi


Book ID
121882326
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
215 KB
Volume
109
Category
Article
ISSN
1089-5639

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✍ Rajeswari Thayumanavan; Buchiramachary Dhevalapally; Kandasamy Sakthivel; Fujie 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 76 KB

Amine-catalyzed Diels-Alder reactions of a,b-unsaturated ketones with dienophiles have been developed. Either (S)-1-(2-pyrrolidinylmethyl)pyrrolidine or L-proline catalyzed the in situ-generation and reaction of 2-amino-1,3-dienes to provide cyclohexanone derivatives in good yield (up to 87%) in one