Mechanism of ruthenium tetroxide-catalysed oxidation of aldoses by alkalineN-bromoacetamide
β Scribed by Ashok K. Singh; Amar Singh; Ranjana Gupta; Madhu Saxena; Bharat Singh
- Publisher
- Springer
- Year
- 1992
- Tongue
- English
- Weight
- 300 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0340-4285
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## Abstract Kinetic investigations on Ru(III)βcatalyzed oxidation of cyclopentanol and cyclohexanol by acidic solution of __N__βbromoacetamide (NBA) in the presence of mercury(II) acetate as a scavenger have been carried out in the temperature range of 30β45Β°C. Similar kinetics was followed by both
## Abstract The kinetics of Ruthenium (III) catalysed oxidation of LβValine by alkaline solution of hexacyanoferrate (III) were studied by following the rate of disappearance of Fe(CN)^3β^. The reaction shows zero order dependence on hexacyanoferrate (III). First order on ruthenium (III). The first
Ruthenium tetroxide selectively oxidizes activated aromatic compounds under mild conditions and has been used for the catalytic oxidation of several different coals. The quantities of the volatile monocarboxylic acids with 26 carbon atoms have been determined by an isotope dilution technique. The am