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Mechanism of reactions of unsaturated ethers and thioethers III: Acid catalyzed addition of water to ethynyl ethers

✍ Scribed by E. J. Stamhuis; W. Drenth

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
504 KB
Volume
80
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The kinetics of the addition of water to ethynyl ethers in aqueous solution were investigated:
equation image

The reaction is general acid catalyzed. This indicates, that a proton transfer is the rate determining step of the reaction:
equation image

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