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Mechanism of reaction of bromine(V) with weak one-electron reducing agents

โœ Scribed by Noyes, Richard M.; Field, Richard J.; Thompson, Richard C.

Book ID
121320786
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
271 KB
Volume
93
Category
Article
ISSN
0002-7863

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The phosphorus-oxygen bond of diastereomerically pure menthyloxyphosphine-boranes was reductively cleaved at -78 "C by lithium naphthalenide or Li-NH3 in excellent yields with almost complete retention of configuration at phosphorus. Chiml tetracoordinate organophosphorus compounds containing a leav