✦ LIBER ✦
Mechanism of primary aliphatic amines oxidation to nitriles by the cuprous chloride - dioxygen - pyridine system.
✍ Scribed by P. Capdevielle; A. Lavigne; D. Sparfel; J. Baranne-Lafont; Kim Cuong Nguyen; M. Maumy
- Publisher
- Elsevier Science
- Year
- 1990
- Tongue
- French
- Weight
- 266 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Primary aliphatic amines are readily oxidized to nitriles by the prt$ormed oxocopper(lI) complex in the Cu(I)chloridelO~lpyridine sysrem. A mechanism is proposed according to kinetic and deuterium
isotope @ects data.