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Mechanism of photosubstitution reactions of square-planar platinum(II) complexes. I. Bromodiethylenetriamineplatinum(II)-nitrite ion system

โœ Scribed by Bartocci, C.; Scandola, F.; Balzani, V.


Book ID
127372316
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
479 KB
Volume
91
Category
Article
ISSN
0002-7863

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Mechanism of photosubstitution reactions
โœ C. Bartocci; A. Ferri; V. Carassiti; F. Scandola ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 457 KB

## The photosubstitution reactions of Pt(Et4dien)Br' have been investigated in aqueous solution by irradiation with 313 nm light. Pt(Et4dien)Hz02' was always formed in acid or neutral solutions, independently of the presence of CT (up to 1 X IO* M) or Br-(up to 1 X 1 0e2 M). Pt(Et,dien)OH' was forme