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Mechanism of oxygenation of cis-stilbene by iron bleomycin

✍ Scribed by Heimbrook, David C.; Carr, Steven A.; Mentzer, Mary A.; Long, Eric C.; Hecht, Sidney M.

Book ID
125897139
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
256 KB
Volume
26
Category
Article
ISSN
0020-1669

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Direct comparison of oxygen transfer by
Direct comparison of oxygen transfer by iron bleomycin and zinc bleomycin
✍ Eric C. Long; Sidney M. Hecht 📂 Article 📅 1988 🏛 Elsevier Science 🌐 French ⚖ 278 KB

A direct comparison has been made of the oxygen transfer abilities of Fe(III), Zn(II), and their respective bleomycin (BLM) complexes. These (chelated) metal ions were treated with iodosobenzene in aqueous methanol containing & or m-stilbene. It was found that oxygen transfer was observed Q& when r