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Mechanism of oxidation of some aliphatic ketones by N-bromosuccinimide in acidic media

✍ Scribed by Bharat Singh; Laiji Pandey; J. Sharma; S.M. Pandey


Publisher
Elsevier Science
Year
1982
Tongue
French
Weight
296 KB
Volume
38
Category
Article
ISSN
0040-4020

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πŸ“œ SIMILAR VOLUMES


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Oxidative kinetics of diethyl ketone in perchloric acid media in the presence of mercuric acetate have been studied by using N-bromosuccinimide (NBS) as oxidant in the temperature range of 25"-50"C. It has been found that the order with respect to NBS is zero while with respect to diethyl ketone and

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## Abstract The kinetics of oxidation of methyl, ethyl, __n__‐propyl, isopropyl, and __n__‐butyl acetates to acetic acid and the corresponding aldehyde by the title oxidant in aqueous HCl medium at 40Β°C has been studied. The reaction shows first‐order with respect to [oxidant] and fractional orders

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Ahatract -The anodic oxidation of aliphatic ketones at a smooth Pt electrode in TFA/Bu,NBF, has been studied. It is shown that, in general, the reaction leads to the formation of a trifluoroacetate ester at a carbon atom remote from the k&o-group; on work up the products were either hydroxy ketones,