Mechanism of oxidation of some aliphatic ketones by N-bromosuccinimide in acidic media
β Scribed by Bharat Singh; Laiji Pandey; J. Sharma; S.M. Pandey
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- French
- Weight
- 296 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
Oxidative kinetics of diethyl ketone in perchloric acid media in the presence of mercuric acetate have been studied by using N-bromosuccinimide (NBS) as oxidant in the temperature range of 25"-50"C. It has been found that the order with respect to NBS is zero while with respect to diethyl ketone and
## Abstract The kinetics of oxidation of methyl, ethyl, __n__βpropyl, isopropyl, and __n__βbutyl acetates to acetic acid and the corresponding aldehyde by the title oxidant in aqueous HCl medium at 40Β°C has been studied. The reaction shows firstβorder with respect to [oxidant] and fractional orders
Ahatract -The anodic oxidation of aliphatic ketones at a smooth Pt electrode in TFA/Bu,NBF, has been studied. It is shown that, in general, the reaction leads to the formation of a trifluoroacetate ester at a carbon atom remote from the k&o-group; on work up the products were either hydroxy ketones,