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Mechanism of oxidation of primary and secondary alcohols by oxopiperidinium salts

✍ Scribed by V. A. Golubev; V. N. Borislavskii; A. L. Aleksandrov


Book ID
118288876
Publisher
Springer
Year
1977
Tongue
English
Weight
656 KB
Volume
26
Category
Article
ISSN
1573-9171

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The cerium(IV) oxidation of isobutanol, isoamyl alcohol isopropyl alcohol, and secondary butanol catalysed by chromium(III) was studied in sulphuric and perchloric acid mixture at 30 Β°C. The reaction was found to proceed with the formation of a chromium(IV) intermediate followed by its complexation