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Mechanism of nitric acid oxidation of acetophenone to dibenzoylfurazan 2-oxide, benzoic acid, and benzoylformic acid

✍ Scribed by Tezuka, Hiroshi; Kato, Megumi; Sonehara, Yukito

Book ID
118127819
Publisher
Royal Society of Chemistry
Year
1985
Tongue
English
Weight
528 KB
Volume
10
Category
Article
ISSN
1472-779X

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## Abstract A detailed picture is given of the mechanisms involved in the oxidation of acetophenones with oxygen to benzoic acids, at 150Β°, using manganese salts as catalysts and butyric acid as solvent. Kinetic studies indicate that the reaction is first‐order with respect to ketone and butyric a