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Mechanism of metal-catalyzed rearrangement of strained cyclobutane and cyclobutene derivatives

✍ Scribed by Pettit, Rowland.; Wristers, J.; Brener, Lazaro.


Book ID
124169997
Publisher
American Chemical Society
Year
1970
Tongue
English
Weight
401 KB
Volume
92
Category
Article
ISSN
0002-7863

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Cyclopropane and Cyclobutane Derivatives
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a-Halogenated amines are formed by cleavage of aminals with acid halides. Analogously, N,N,N',N'-tetraalkylmethylenediamines react with sulfonic anhydrides t o yield dialkylmethyleneimonium sulfonates and dialkylsulfonamides. Tetraethyl pyrophosphate reacts with aminals or a-dialkylamino ethers to p