Mechanism of manganese porphyrin-catalyzed oxidation of alkenes. Role of manganese(IV)-oxo species
β Scribed by Arasasingham, Ramesh D.; He, Gong Xin; Bruice, Thomas C.
- Book ID
- 121390658
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 805 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The intrinsic reactivity of a manganese(V)βoxo porphyrin complex, a typically fleeting intermediate in catalytic oxidation reactions in solution, has been elucidated in a study focused on its gasβphase ionβchemistry. The naked highβvalent Mn^V^βoxo porphyrin intermediate **1** ([(tpfpp)