Mechanism of Isotactic Polypropylene Formation with C1-Symmetric Metallocene Catalysts
✍ Scribed by Miller, Stephen A.; Bercaw, John E.
- Book ID
- 115522512
- Publisher
- American Chemical Society
- Year
- 2006
- Tongue
- English
- Weight
- 397 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0276-7333
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## Abstract 1‐Butene polyinsertion promoted by two typical __C__~2~‐symmetric zirconocene catalysts (i.e. __rac__‐ethylenebis(1‐indenyl)ZrCl~2~ (1) and __rac__‐dimethylsilylbis(1‐indenyl)ZrCl~2~) (2) was investigated under both hydrooligomerization and polymerization conditions and compared with th
## Abstract Polymerization of propene was conducted at 40°C under reduced pressure (0.35 – 1.0 atm) using the C~1~‐Symmetric __threo__‐^i^Pr(3‐^t^BuCp)(3‐^t^BuInd)ZrCl~2~/MAO and TiCl~4~/MgCl~2~/Al(^i^Bu)~3~ catalyst systems and the effect of propene pressure on the microstructure of the resulting