𝔖 Bobbio Scriptorium

✦ LIBER ✦

Mechanism of insertion of isocyanides across the PdC bond in the pyridyl complex [PdCl{C5H3N(6-Cl)-C2}(diphos)] (Diphos = 1,2-bis(diphenylphosphino)ethane)

✍ Scribed by A. Campagnaro; A. Mantovani; P. Uguagliati

Book ID: 108328206
Publisher: Elsevier Science
Year: 1985
Tongue: English
Weight: 453 KB
Volume: 99
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)86038-7

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Formation of an endo-type nine-membered

Formation of an endo-type nine-membered metallocycle via insertion of diphenylacetylene into the σ(Pd-Csp2, ferrocene) bond. X-Ray crystal structure of [Pd{{(C6H5CCC6H5)2(η5-C5H3)CHNCH2C6H5}-Fe(η5-C5H5)}Cl]·CH2Cl2

✍ Concepción López; Xavier Solans; David Tramuns 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 837 KB

Synthesis of the First C-2 Cyclopalladat

Synthesis of the First C-2 Cyclopalladated Derivatives of 1,3-Bis(2-pyridyl)benzene. Crystal Structures of [Hg(N-C-N)Cl], [Pd(N-C-N)Cl], and [Pd 2 (N-C-N) 2 (μ-OAc)] 2 [Hg 2 Cl 6 ]. Catalytic Activity in the Heck Reaction

✍ Soro, Barbara; Stoccoro, Sergio; Minghetti, Giovanni; Zucca, Antonio; Cinellu, M 📂 Article 📅 2005 🏛 American Chemical Society 🌐 English ⚖ 192 KB

Preparation and reactions of palladium(I

Preparation and reactions of palladium(II) complexes with C2-bonded heteroaromatic ligands trans[PdCl(RN)(PPh3)2] (RN = 2-pyridyl, 2-pirazyl, 2-pyrimidyl group). A new reaction pathway in the insertion of isocyanides into the Pdc bond of trans-[PdXR(L)2] compounds

✍ Roberta Bertani; Adriano Berton; Francesca Di Bianca; Bruno Crociani 📂 Article 📅 1986 🏛 Elsevier Science 🌐 English ⚖ 1011 KB

Insertion reaction of isocyanide into th

Insertion reaction of isocyanide into the PtC bonds of 2,5-thienylene-bridged diplatinum complexes and 2-thienyl platinum complexes: molecular structure of Cl(Et3P)2PtC(NC6H4OMe-p)C4H2SC (NC6H4OMe-p)Pt(PEt3)2Cl·CH2Cl2

✍ Kiyotaka Onitsuka; Kazuyoshi Murakami; Kenji Matsukawa; Kenkichi Sonogashira; To 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 663 KB

The nature of the phosphorus-metal bond

The nature of the phosphorus-metal bond in triphenylphosphine—transition metal complexes (Pd[P(C6H5)3]4, Rh(CO)Cl[P(C6H5)3]2 and Ir(CO)Cl[P(C6H5)3]2. A direct determination of the importance of P3d and PC σ∗ orbitals in ‘back-bonding’ by X-ray emission spectroscopy

✍ Caroline Bourg; Stuart Gamblin; David S Urch 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 719 KB

Palladium-Assisted Formation of Carbon−C

Palladium-Assisted Formation of Carbon−Carbon Bonds. 7. 1 Reactions of (2,3,4-Trimethoxy-6-X-phenyl)palladium Complexes with Alkynes (X = C(O)NHBu t ) and Isocyanides (X = C(O)NHBu t , C(O)Me, CHO): Crystal and Molecular Structures of [Pd{C 6 H{C(O)NHBu t }-6-(OMe) 3 -2,3,4}(bpy)](CF 3 SO 3 ), [Pd{C(CO 2 Me)C(CO 2 Me)C 6 H{C(O)NHBu t }-6-(OMe) 3 -2,3,4)}- Cl(PPh 3 )], [Pd{C(NXy)C 6 H{C(O)NHBu t }-6-(OMe) 3 -2,3,4}- (bpy)](CF 3 SO 3 ), and the Ketenimine 2-(2,6-Dimethylphenyl)-1-(((2,6-dimethylphenyl)imino)- methylene)-5,6,7-trimethoxy-3-oxoisoindoline

✍ Vicente, José; Abad, José-Antonio; Shaw, Kenneth F.; Gil-Rubio, Juan; Ramírez de 📂 Article 📅 1997 🏛 American Chemical Society 🌐 English ⚖ 527 KB