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Mechanism of Homogeneous Ir(III) Catalyzed Regioselective Arylation of Olefins

โœ Scribed by Oxgaard, Jonas; Muller, Richard P.; Goddard, William A.; Periana, Roy A.


Book ID
126453342
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
308 KB
Volume
126
Category
Article
ISSN
0002-7863

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Regioselective hydrophenylation of olefi
โœ Takaya Matsumoto; Roy A Periana; Douglas J Taube; Hajime Yoshida ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 293 KB

The novel, anti-Markovnikov, arylation of olefins with benzene to produce straight-chain alkylbenzenes with higher selectivity than branched alkylbenzenes is catalyzed by [Ir(-acac-O,O ,C 3 )(acac-O,O )(acac-C 3 )] 2 (acac = acetylacetonato), 1 [J. Am. Chem. Soc. 122 (2000) 7414]. The reaction of be