## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
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Mechanism of Homogeneous Iridium-Catalyzed Alkylation of Amines with Alcohols from a DFT Study
โ Scribed by Balcells, David; Nova, Ainara; Clot, Eric; Gnanamgari, Dinakar; Crabtree, Robert H.; Eisenstein, Odile
- Book ID
- 117997821
- Publisher
- American Chemical Society
- Year
- 2008
- Tongue
- English
- Weight
- 272 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0276-7333
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A new effective catalytic system consisting of [Cp\*IrCl 2 ] 2 /K 2 CO 3 (Cp\*=pentamethylcyclopentadienyl) for the N-alkylation of primary amines with alcohols has been developed. As an example, the reaction of aniline with benzyl alcohol in the presence of [Cp\*IrCl 2 ] 2 (5.0 mol%Ir) and K 2 CO 3