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Mechanism of heterogeneous gas phase dehydration of 1-methylcyclohexanol catalysed by metal(IV) phosphates

✍ Scribed by Robert A.W. Johnstone; Jun-Yao Liu; David Whittaker


Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
134 KB
Volume
174
Category
Article
ISSN
1381-1169

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Catalysis of gas and liquid phase ionic
✍ M.Conceicao Cruz Costa; Robert A.W. Johnstone; David Whittaker πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 713 KB

Gas-phase rearrangements of (Y-and P-pinene catalysed by metal( IV) phosphate polymers have been studied. The phosphates catalyse carbocation rearrangements in both substrates as expected, but catalysis of a modified radical rearrangement of cY-pinene to yield cu-pyronene has also been observed. Red