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Mechanism of Formation of Cholesterylisothiuronium Salts from i-Cholesteryl Methyl Ether 1a

โœ Scribed by Pearson, R. G.; Subluskey, Lee A.; King, L. Carroll

Book ID
127005472
Publisher
American Chemical Society
Year
1948
Tongue
English
Weight
310 KB
Volume
70
Category
Article
ISSN
0002-7863

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The recent proposal that ionized phytyl methyl ether [C,,H,,(CH,)C =CHCH,OCHl'] undergoes an allylic rearrangement to ionized isophytyl methyl ether [CH, = CHC(C,,H,,XCH,)OCH,f'] before elimination of an alkyl radical is discussed. Both literature precedent and new results in which the structure of