Mechanism of formation and spectroscopic characterization of the methylviologen radical cation, MV+, in the solid state

✍ Scribed by O. Poizat; C. Sourisseau; C. Giannotti

• Publisher: Elsevier Science
• Year: 1985
• Tongue: English
• Weight: 162 KB
• Volume: 122
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(85)85491-9

✦ Synopsis

The mcthylviologen radical cation MV + has been generated in lhe solid sLate either from the MVC12 Salk, by heating or by laser irradiation at 6471 br. or horn the MV'+ cation intercalated in the CdPS, lamellar hosl lake. by chemical reduclion. In each case the mechanism of formarion is discussed and the spectroscopic characterizaion (IR. UV and visible absoqions) of lhc radical spccics is given.