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Mechanism of Electron Transfer in Heme Proteins and Models: The NMR Approach

✍ Scribed by Simonneaux, Gérard; Bondon, Arnaud

Book ID
120487717
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
515 KB
Volume
105
Category
Article
ISSN
0009-2665

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## Abstract The chemical shifts of fluorine in difluorovinyl deuteroporphyrin iron complexes were shown to be very sensitive to the spin state of the metal and the nature of the ligand(s). Reconstituted myoglobin was used as a model heme protein with an exchangeable heme. Large variations in the fl