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Mechanism of Electrocyclic Ring-Opening of Diphenyloxirane: 40 Years after Woodward and Hoffmann

✍ Scribed by Jana Friedrichs; Irmgard Frank


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
380 KB
Volume
15
Category
Article
ISSN
0947-6539

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Electrocyclic Ring Opening of cis-Bicycl
✍ Carlos Silva López; Olalla Nieto Faza; Ángel R. de Lera 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 206 KB

## Abstract The dubbed anti‐Woodward–Hoffmann ring‐opening reaction of __cis__‐bicyclo[4.2.0]oct‐7‐ene to yield __cis__,__cis__‐cycloocta‐1,3‐diene has been intensively studied with robust, high‐level computational methods. This reaction has been found to proceed through a conrotatory allowed pathw