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Mechanism of dispersion polymerization ofL-lactide initiated with 2,2-dibutyl-2-stanna-1,3-dioxepane

โœ Scribed by S. Sosnowski; S. Slomkowski; A. Lorenc; H. R. Kricheldorf

Book ID
106070272
Publisher
Springer
Year
2002
Weight
196 KB
Volume
280
Category
Article
ISSN
0340-255X

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BF 3 rOEt 2 -initiated polymerizations of 2-methylene-1,3-dioxepane gave polymers composed of both ring-retained and ring-opened structures. The ring-opening content increased with an increase in polymerization temperature. Poly(4,7-dimethyl-2-methylene-1,3-dioxepane) propagated slower during BF 3 r