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Mechanism of dediazoniation of arenediazonium salts with triphenylphosphine and trialkyl phosphites. Generation of cation radicals from trivalent phosphorus compounds and their reactions

✍ Scribed by Yasui, Shinro; Fujii, Masayuki; Kawano, Chihiro; Nishimura, Yukihiro; Shioji, Kosei; Ohno, Atsuyoshi

Book ID: 125498187
Publisher: Royal Society of Chemistry
Year: 1994
Tongue: English
Weight: 918 KB
Volume: 2
Category: Article
ISSN: 1472-779X
DOI: 10.1039/P29940000177

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Dediazoniation of arenediazonium salts with trivalent-phosphorus compounds. Tool for examination of the reactivity of phosphorus-centered radicals

✍ Shinro Yasui; Kosei Shioji; Atsuyoshi Ohno 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 885 KB

Trialkyl phosphites (l), dialkyl phenylphosphinites (2), and alkyl diphenylphosphonites (3) as well as 2-phenyl-1,3,2-dioxaphospholan (4a) and 2-phenyl-l,3,2-dioxaphosphorinan (4b) give rise to dediazoniation of ar-