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Mechanism of decomposition of alkyl diphenylphosphinates

โœ Scribed by Berlin, K. Darrell; Morgan, John G.; Peterson, Melbert E.; Pivonka, W. C.

Book ID
126823303
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
742 KB
Volume
34
Category
Article
ISSN
0022-3263

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The kinetics of the gas-phase decomposition of ethyl, isopropyl, and t -butyl isocyanates have been studied in the temperature range of 380-530OC. t -Butyl isocyanate decomposes almost exclusively by a unimolecular route to isobutene and HNCO, but in EtNCO and i - PrNCO this route competes with a fr