Mechanism of CO oxidation in excess H2over CuO/CeO2catalysts: ESR and TPD studies
✍ Scribed by A. N. Il’ichev; A. A. Firsova; V. N. Korchak
- Book ID
- 110170765
- Publisher
- Springer
- Year
- 2006
- Tongue
- English
- Weight
- 200 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0023-1584
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The influence of the surface area, crystal size of the support and the Cu loading (3-9 wt.%) on the catalytic behavior of CuO/CeO 2 catalysts was investigated in the preferential CO oxidation (PROX) reaction. Two ceria samples were used: a high-surface area one (SCe) prepared by the templating techn
The kinetics of CO and H 2 oxidation over a CuO-CeO 2 catalyst were simultaneously investigated under reaction conditions of preferential CO oxidation (PROX) in hydrogen-rich mixtures with CO 2 and H 2 O. An integral packed-bed tubular reactor was used to produce kinetic data for power-law kinetics
A C T CuO-CeO 2 catalysts were prepared by hydrothermal method. The influence of Cu loadings on the catalytic performance of CuO-CeO 2 catalysts for the preferential oxidation of CO in excess H 2 has been studied and their physicochemical properties were characterized by X-ray powder diffraction (XR