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Mechanism of base hydrolysis for [Co(pentaamine)X]2+ ions. Hydrolysis and rearrangement for the sulfur-bonded trans-[(en)2NH3CoSCN]2+ ion

โœ Scribed by Buckingham, D. A.; Creaser, I. I.; Marty, W.; Sargeson, A. M.


Book ID
121378046
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
830 KB
Volume
11
Category
Article
ISSN
0020-1669

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On the mechanism of the Hg2+ and base in
โœ David A. Buckingham; Werner Marty; Alan M. Sargeson ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 894 KB

## Acid hydrolysis of the ester function in A-( -)589-fi2-(RR)-[Co (trien) (glyOEt)C1I2+ (( -)-1) produces optically pure A-( -)589$2-(RR)-[CO (trien) (glyOH)C1I2+ (( -)-4). Hg2+ induced removal of chloride in (-)-4 follows the rate law kobs=kHg [Hg2+] with kHg=(1.36+0.03)x 1 0 -2 ~-l s -' , 25",