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Mechanism of asymmetric homogeneous hydrogenation. Rhodium-catalyzed reductions with deuterium and hydrogen deuteride

โœ Scribed by Brown, John M.; Parker, David

Book ID
120881214
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
958 KB
Volume
1
Category
Article
ISSN
0276-7333

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The mechanism of asymmetric hydrogenatio
The mechanism of asymmetric hydrogenations catalyzed by chiral pyrrolidinephosphine-rhodium complexes
โœ Kazuo Achiwa; Yoko Ohga; Yoichi Iitaka; Hazime Saito ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

Effective catalytic asymmetric hydrogenations catalyzed by chiral pyrrolidinephosphine-rhodium complexes have been proven to be useful for the preparation of optically active a-amino acids @3-91%)2'3), isoquinoline salsolidine (45%)6) cc-hydroxy esters (78.5%)4'5), R-(-)-pantolactone C80.5-86.7%17'g