Mechanism of anodic oxidation of chlorate to perchlorate on platinum electrodes
โ Scribed by L. J. J. Janssen; P. D. L. Heyden
- Publisher
- Springer
- Year
- 1995
- Tongue
- English
- Weight
- 935 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0021-891X
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๐ SIMILAR VOLUMES
Cyclic voltammetry experiments performed in acid solutions of cyclohexene on platinized platinum anodes show that platinum oxide must play a role in the anodic oxidation of the hydrocarbon through a mechanisticscheme of the type proposed by Gilman[lO].
The mechanism of anodic oxidation of cyanide on platinum electrode was studied electrochemically and chemically. Cyanide was oxidized at a first order with respect to hydroxyl ion and at zero with respect IO cyanide ion on the rate determining step. On the other hand. the potential controlled coulom