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Mechanism of anion exchange on thorium tetracyclohexylamine

โœ Scribed by S. Iqbal; M. Kamoonpuri; J.P. Rawat

Publisher
Elsevier Science
Year
1992
Weight
273 KB
Volume
17
Category
Article
ISSN
0923-1137

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โœ Kathleen E. Bainbridge; William P. Dailey ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 235 KB

Treatment of isotopically labeled bromophenyldiazirine containing one 15N atom with azide ion produces benzonitrile which contains 50% 15N. This suggests that N-azidodiazirines are intermediates in the reaction. Ab initio calculations predict that N-azidodiazirines will have a very low barrier to de