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Mechanism of Amine-Catalyzed Reaction of Isocyanates with Hydroxyl Compounds

✍ Scribed by Farkas, Adalbert; Strohm, P. F.


Book ID
120405645
Publisher
American Chemical Society
Year
1965
Weight
693 KB
Volume
4
Category
Article
ISSN
0196-4313

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## Abstract The plot of rate constants vs. pH for the dehydration step of the reaction between furfural and 5‐nitrofurfural with hydroxylamine, __N__‐methylhydroxylamine, and __O__‐methylhydroxylamine, shows two regions corresponding to the oxonium ion‐catalyzed and spontaneous dehydration. The oxo