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Mechanism of acetylene–chlorine mixture explosion initiated by small additions of oxygen

✍ Scribed by A. F. Revsin


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
222 KB
Volume
15
Category
Article
ISSN
0538-8066

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✦ Synopsis


An improved radical-chain scheme of acetylene-chlorine mixture explosion initiated by small additions of oxygen is proposed. It includes among others the three-body formation of chemically activated state (2) and describes the inhibiting effect of oxygen below the explosion limit.

CH. * * + C12

CzH2Cl' + Clz + C2HzClz + C1.

CzHzCl.