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Mechanism of acetylene polymerization on different types of catalysts. synthesis of high stable polyacetylene

✍ Scribed by Kobryanskii, V.M.

Book ID
123191526
Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
211 KB
Volume
55
Category
Article
ISSN
0379-6779

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## Abstract The new carbazole‐containing acetylene monomers, 2‐ethynyl‐9‐__tert__‐butoxycarbonylcarbazole (1) and 3‐ethynyl‐9‐__tert__‐butoxycarbonylcarbazole (2) were synthesized and polymerized with Rh^+^(nbd)[__η__^6^–C~6~H~5~B^−^(C~6~H~5~)~3~], [(nbd)RhCl]~2~–Et~3~N, [(nbd)RhCl]~2~–KN(SiMe~3~)~