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Mechanism of Abstraction Reactions of Dimetallenes (R 2 XXR 2 ; X = C, Si, Ge, Sn, Pb) with Halocarbons: A Theoretical Study

✍ Scribed by Su, Ming-Der


Book ID
127273079
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
486 KB
Volume
43
Category
Article
ISSN
0020-1669

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A comprehensive theoretical study on the
✍ Yi Ren; San-Yan Chu πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 English βš– 244 KB

Gas phase identity ion pair S N 2 reactions at nitrogen LiX + NH 2 X ! XNH 2 + LiX (X ΒΌ F, Cl, Br and I) are investigated at the G2M(+) level. Two reaction mechanisms, inversion and retention, are proposed. Results indicate the inversion mechanism is favorable for all halogens. Including Li in the a